加藤 研一 の個人ページ

出版物 / Publications >> 他の業績 / Others

  • 日本語 & English
  • 2024/04/13

    • 生越研究室 / Ogoshi group（2020/04 - present）

    原著論文 / Original papers

    1. "Self-Inclusion Complexation of Electron-Accepting Guest into Electron-Donating Cyclic Host by Photoexcitation"
      Keisuke Wada, Yuuya Nagata, Luxia Cui, Toshikazu Ono, Shigehisa Akine, Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Tomoki Ogoshi,*
      Angew. Chem. Int. Ed. 2024, 63, e202404409. (DOI: 10.1002/anie.202404409, 2024/04/XX)
      2.
    2. "Exciplex Formation by Complexation of an Electron-Accepting Guest in an Electron-Donating Pillar[5]arene Host Liquid"
      Tomoki Ogoshi,* Shogo Azuma, Keisuke Wada, Yuko Tamura, Kenichi Kato, Shunsuke Ohtani, Takahiro Kakuta, Tada-aki Yamagishi,
      J. Am. Chem. Soc. 2024, 146, 9828-9835. (DOI: 10.1021/jacs.3c14582, 2024/04/02)
    3. "Solid-State Emissive Pillar[6]arene Derivatives Embedded with Nitrogen into Bridging Moieties"
      Shunsuke Ohtani,* Kazeto Nakaguchi, Kenichi Kato, Tomoki Ogoshi,*
      Chem. Asian J. 2024, 19, e202400106. (DOI: 10.1002/asia.202400106, 2024/02/21)
    4. "Alkoxylated Fluoranthene-Fused [3.3.3]Propellanes: Facile Film Formation against High π-Core Content"
      Kenichi Kato,* Yuta Uchida, Tomoya Kaneda, Tomoki Tachibana, Shunsuke Ohtani, Tomoki Ogoshi,*
      Chem. Asian J. 2024, 19, e202400080. (DOI: 10.1002/asia.202400080, 2024/02/21)
    5. "Silapillar[n]arenes: Their Enhanced Electronic Conjugation and Conformational Versatility"
      Shunsuke Ohtani,* Shigehisa Akine, Kenichi Kato, Shixin Fa, Tan-hao Shi, Tomoki Ogoshi,*
      J. Am. Chem. Soc. 2024, 146, 4695-4703. (DOI: 10.1021/jacs.3c12093)
    6. "Friedel-Crafts Acylation for Accessing Multi-Bridge-Functionalized Large Pillar[n]arenes"
      Tan-Hao Shi, Shigehisa Akine, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi,*
      Angew. Chem. Int. Ed. 2024, 63, e202318268. (DOI: 10.1002/anie.202318268)
    7. "Stable planar chirality of arylated Pillar[6]arene and its thermal response"
      Keisuke Wada, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi,*
      Tetrahedron Lett. 2024, 135, 154891. (DOI: 10.1016/j.tetlet.2023.154891)
    8. "Circularly polarized luminescence from a common alkoxy pillar[5]arene and its co-aggregates with π-conjugated rods"
      Kenichi Kato,* Ryo Iwano, Shun Tokuda, Kiichi Yasuzawa, Masayuki Gon, Shunsuke Ohtani, Shuhei Furukawa, Kazuo Tanaka, Tomoki Ogoshi,*
      Aggregate 2024, 5, e482. (DOI: 10.1002/agt2.482)
    9. "Size-Selective Capture of Fluorocarbon Gases and Storage of Volatile Halogenated Organic Vapors with Low Boiling Points by Molecular-Scale Cavities of Crystalline Pillar[n]quinones"
      Shunsuke Ohtani, Katsuto Onishi, Keisuke Wada, Tomoki Hirohata, Shinsuke Inagi, Jenny Pirillo, Yuh Hijikata, Motohiro Mizuno, Kenichi Kato, Tomoki Ogoshi,*
      Adv. Funct. Mater. 2024, 34, 2312304. (DOI: 10.1002/adfm.202312304)
    10. "Diastereoselective Rotaxane Synthesis with Pillar[5]arenes via Co-crystallization and Solid State Mechanochemical Processes"
      Keisuke Wada, Kiichi Yasuzawa, Shixin Fa, Yuuya Nagata, Kenichi Kato, Shunsuke Ohtani, Tomoki Ogoshi,*
      J. Am. Chem. Soc. 2023, 145, 15324-15330. (DOI: 10.1021/jacs.3c02919)
    11. “Efficient synthesis and unit-selective π-extension of π-fused [4.3.3]propellane as a chiral building block”
      Kenichi Kato,* Seigo Tanaka, Nobuyoshi Seto, Keisuke Wada, Masayuki Gon, Shixin Fa, Shunsuke Ohtani, Kazuo Tanaka, Tomoki Ogoshi,*
      Chem. Commun. 2023, 59, 7080-7083. (DOI: 10.1039/d3cc01809a)
    12. “Adaptive Planar Chirality of Pillar[5]arenes Invertible by n-Alkane Lengths”
      Keisuke Adachi, Shixin Fa,* Keisuke Wada, Kenichi Kato, Shunsuke Ohtani, Yuuya Nagata, Shigehisa Akine, Tomoki Ogoshi,*
      J. Am. Chem. Soc. 2023, 145, 8114-8121. (DOI: 10.1021/jacs.3c01019)
    13. “Per-Arylation of Pillar[n]arenes: An Effective Tool to Modify the Properties of Macrocycles”
      Kenichi Kato,* Tomoya Kaneda, Shunsuke Ohtani, Tomoki Ogoshi,*
      J. Am. Chem. Soc. 2023, 145, 6905-6913. (DOI: 10.1021/jacs.3c00397)
    14. “Dynamic-to-Static Planar Chirality Conversion in Pillar[5]arenes Regulated by Guest Solvents or Amplified by Crystallization”
      Keisuke Wada, Misaki Suzuki, Takahiro Kakuta, Tada-aki Yamagishi, Shunsuke Ohtani, Shixin Fa, Kenichi Kato, Shigehisa Akine, Tomoki Ogoshi,*
      Angew. Chem. Int. Ed. 2023, 62, e202217971. (DOI: 10.1002/anie.202217971)
    15. “Discrete chiral organic nanotubes by stacking pillar[5]arenes using covalent linkages”
      Tan-Hao Shi, Shixin Fa, Yuuya Nagata, Keisuke Wada, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi,*
      Cell Rep. Phys. Sci. 2022, 3, 101173. (DOI: 10.1016/j.xcrp.2022.101173)
    16. “A Twisted Chiral Cavitand with 5-Fold Symmetry and Its Length-Selective Binding Properties”
      Tan-Hao Shi, Yuuya Nagata, Shigehisa Akine, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi,*
      J. Am. Chem. Soc. 2022, 144, 23677-23684. (DOI: 10.1021/jacs.2c11225)
    17. “Real-time chirality transfer monitoring from statistically random to discrete homochiral nanotubes”
      Shixin Fa, Tan-hao Shi, Suzu Akama, Keisuke Adachi, Keisuke Wada, Seigo Tanaka, Naoki Oyama, Kenichi Kato, Shunsuke Ohtani, Yuuya Nagata, Shigehisa Akine, Tomoki Ogoshi,*
      Nat. Commun. 2022, 13, 7378. (DOI: 10.1038/s41467-022-34827-z)
    18. “Cyclic arrays of five pyrenes on one rim of a planar chiral pillar[5]arene”
      Kenichi Kato,* Shunsuke Ohtani, Masayuki Gon, Kazuo Tanaka, Tomoki Ogoshi,*
      Chem. Sci. 2022, 13, 13147-13152. (DOI: 10.1039/d2sc04168e)
    19. “Room-temperature Ring-opening Polymerization of δ-Valerolactone and ε-Caprolactone Caused by Uptake into Porous Pillar[5]arene Crystals”
      Kenichi Kato, Koki Maeda, Motohiro Mizuno, Yuta Nishina, Shixin Fa, Shunsuke Ohtani, Tomoki Ogoshi,*
      Angew. Chem. Int. Ed. 2022, 61, e202212874. (DOI: 10.1002/anie.202212874)
    20. “Selective Gas Adsorption on Molecular Solids of a Hydrogen-bonding [3.3.3]Propellane”
      Kenichi Kato,* Tatsuki Hiroi, Nobuyoshi Seto, Shunsuke Ohtani, Tomoki Ogoshi,*
      Chem. Lett. 2022, 51, 975-977. (DOI: 10.1246/cl.220320)
    21. “Discrete Macrocycles with Fixed Chirality and Two Distinct Sides: Dipole-Dependent Chiroptical Response”
      Kenichi Kato,* Yuta Kurakake, Shunsuke Ohtani, Shixin Fa, Masayuki Gon, Kazuo Tanaka, Tomoki Ogoshi,*
      Angew. Chem. Int. Ed. 2022, 61, e202209222. (DOI: 10.1002/anie.202209222)
    22. “Synthesis of Hexa-Aminated Trinaphtho[3.3.3]propellane and Its Porous Polymer Solids with Alkane Adsorption Properties”
      Kenichi Kato,* Nobuyoshi Seto, Koki Chida, Takeharu Yoshii, Motohiro Mizuno, Hirotomo Nishihara, Shunsuke Ohtani, Tomoki Ogoshi,*
      Bull. Chem. Soc. Jpn. 2022, 95, 1296-1302. (DOI: 10.1246/bcsj.20220180, Selected Paper)
    23. "Hybrid Chiral MoS2 Layers for Spin-polarized Charge Transport and Spin-dependent Electrocatalytic Applications"
      Zhiyun Bian, Kenichi Kato, Tomoki Ogoshi, Zhou Cui, Baisheng Sa, Yusuke Tsutsui, Shu Seki, Masayuki Suda,*
      Adv. Sci. 2022, 9, 2201063. (DOI: 10.1002/advs.202201063)
    24. “CPL on/off control of an assembled system by water soluble macrocyclic chiral sources with planar chirality”
      Shixin Fa, Takuya Tomita, Keisuke Wada, Kazuma Yasuhara, Shunsuke Ohtani, Kenichi Kato, Masayuki Gon, Kazuo Tanaka, Takahiro Kakuta, Tada-aki Yamagishi, Tomoki Ogoshi,*
      Chem. Sci. 2022, 13, 5846-5853. (DOI: 10.1039/d2sc00952h)
    25. "State- and Water Repellency-Controllable Molecular Glass of Pillar[5]arene with Fluoroalkyl Groups by Guest Vapor"
      Katsuto Onishi, Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Yoko Sakata, Shigehisa Akine, Moe Ogasawara, Hitoshi Asakawa, Shusaku Nagano, Yoshinori Takashima, Motohiro Mizuno, Tomoki Ogoshi,*
      Chem. Sci. 2022, 13, 4082-4087. (DOI: 10.1039/d2sc00828a)
    26. "Pre-regulation of the Planar Chirality of Pillar[5]arenes for Preparing Discrete Chiral Nanotubes"
      Shixin Fa, Keisuke Adachi, Yuuya Nagata, Kouichi Egami, Kenichi Kato, Tomoki Ogoshi,*
      Chem. Sci. 2021, 12, 3483-3488. (DOI: 10.1039/d1sc00074h, Back Cover)
    27. "Thermally Responsive Poly(ethylene oxide)-based Polyrotaxanes Bearing Hydrogen-bonding Pillar[5]arene Rings"
      Kenichi Kato, Katsuto Onishi, Koki Maeda, Masafumi Yagyu, Shixin Fa, Takahiro Ichikawa, Motohiro Mizuno, Takahiro Kakuta, Tada-aki Yamagishi, Tomoki Ogoshi,*
      Chem. Eur. J. 2021, 27, 6435-6439. (DOI: 10.1002/chem.202005099, Front Cover)
    28. "Sequential Chiral Induction and Regulator-assisted Chiral Memory of Pillar[5]arenes"
      Shixin Fa, Koichi Egami, Keisuke Adachi, Kenichi Kato, Tomoki Ogoshi,*
      Angew. Chem. Int. Ed. 2020, 59, 20353-20356. (DOI: 10.1002/anie.202010050, Inside Back Cover)

    総説等 / Reviews & Book chapters

    1. "Alignment and Dynamic Inversion of the Planar Chirality in Pillar[n]arenes"
      Kenichi Kato, Shixin Fa, Tomoki Ogoshi,*
      Angew. Chem. Int. Ed. 2023, 62, e202308316. (DOI: 10.1002/anie.202308316)
    2. "Host-guest behavior of pillar[n]arene-based supramolecular assemblies"
      Tan-Hao Shi, Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Tomoki Ogoshi,*
      Trends Chem. 2023, 5, 537-550. (DOI: 10.1016/j.trechm.2023.04.004)
    3. "Noncovalently bound and mechanically interlocked systems using pillar[n]arenes"
      Kenichi Kato, Shixin Fa, Shunsuke Ohtani, Tan-hao Shi, Albert M. Brouwer,* Tomoki Ogoshi,*
      Chem. Soc. Rev. 2022, 51, 3648-3687. (DOI: 10.1039/d2cs00169a)
    4. "Host-Guest Chemistry Based on Solid-State Pillar[n]arenes"
      Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Tomoki Ogoshi,*
      Coord. Chem. Rev. 2022, 462, 214503. (DOI: 10.1016/j.ccr.2022.214503)
    5. "Discrete and Continuous One-Dimensional Channels Based on Pillar[n]arenes"
      Kenichi Kato, Shunsuke Ohtani, Shixin Fa, Tomoki Ogoshi,*
      Bull. Chem. Soc. Jpn. 2021, 94, 2319-2328. (DOI: 10.1246/bcsj.20210243)

    その他 / Others

    1. 「柱状分子ピラーアレーンに基づくチューブ構造の創成」
      加藤 研一、FA Shixin、生越 友樹
      超分子研究会アニュアルレビュー、No. 41 (2020)、高分子学会、2021年、pp. 8-9（レビュー）
    2. 「ピラー[n]アレーンを基にしたソフトクリスタルの開発」
      和田 圭介、加藤 研一、生越 友樹
      日本結晶学会誌、第63巻 第1号、日本結晶学会、2021年、pp. 8-15（DOI: 10.5940/jcrsj.63.8、特集記事）
    3. 「環状分子を非対称化しよう — 二面性ピラー[5]アレーンの化学」
      加藤 研一、FA Shixin、生越 友樹
      化学、第75巻 第12号、化学同人、2020年、pp. 64-65（最新のトピックス）

    大須賀研究室 / Osuka group（2014/04 - 2020/03）

    原著論文 / Original papers

    1. “Double helices of dissymmetrical α,α'-disubstituted tripyrrins”
      Y. Fukuda, Y. Akamatsu, M. Umetani, K. Kise, K. Kato, A. Osuka, T. Tanaka,
      Org. Biomol. Chem. 2023, 21, 1158-1162. (DOI: 10.1039/d2ob02125k)
    2. “A Robust Triplet Porphyrin-Stabilized Carbon Diradical”
      K. Wang, L. Xu, M. Zhou, A. Nakai, K. Kato, K. Furukawa, T. Tanaka, A. Osuka, J. Song,
      Angew. Chem. Int. Ed. 2021, 60, 7002-7006. (DOI: 10.1002/anie.202015356)
    3. "Propeller-shaped Semi-fused Porphyrin Trimers: Molecular-symmetry-dependent Chiroptical Response"
      K. Kato, A. Osuka,
      Chem. Eur. J. 2020, 26, 10217-10221. (DOI: 10.1002/chem.202002157)
    4. "Helically Twisted Benzene-1,3,5-triamine-fused Porphyrin Dimers"
      K. Kato, A. Osuka,
      Chem. Lett. 2020, 49, 517-520. (DOI: 10.1246/cl.200115, Editor's Choice)
    5. "Cyclophane-type Chlorin Dimers from Dynamic Covalent Chemistry of 2,18-Porphyrinyl Dicyanomethyl Diradicals"
      B. Adinarayana, K. Kato, D. Shimizu, T. Tanaka, K. Furukawa, A. Osuka,
      Angew. Chem. Int. Ed. 2020, 59, 4320-4323. (DOI: 10.1002/anie.201914480)
    6. "Phenylene-bridged Porphyrin meso-Oxy Radical Dimers"
      T. Yamamoto, K. Kato, D. Shimizu, T. Tanaka, A. Osuka,
      Chem. Asian J. 2019, 14, 4031-4034. (DOI: 10.1002/asia.201901033)
    7. "meta- and para-Phenylenediamine-fused Porphyrin Dimers: Synthesis and Magnetic Interactions in Their Dication Diradicals"
      K. Kato, A. Osuka,
      Angew. Chem. Int. Ed. 2019, 58, 8546-8550. (DOI: 10.1002/anie.201901939)
    8. "Aromatic and Antiaromatic Cyclophane-type Hexaphyrin Dimers"
      A. Nakai, T. Yoneda, S.-i. Ishida, K. Kato, A. Osuka,
      Chem. Asian J. 2019, 14, 256-260. (DOI: 10.1002/asia.201801751)
    9. "A Stable Trimethylenemethane Triplet Diradical Based on a Trimeric Porphyrin Fused π-System"
      K. Kato, K. Furukawa, A. Osuka,
      Angew. Chem. Int. Ed. 2018, 57, 9491-9494. (DOI: 10.1002/anie.201804644)
    10. "Porphyrin-Based Air-Stable Helical Radicals"
      K. Kato, K. Furukawa, T. Mori, A. Osuka,
      Chem. Eur. J. 2018, 24, 572-575. (DOI: 10.1002/chem.201705291, Very Important Paper, highlighted in Synfacts 2018, 14, 0143)
    11. "Cyclic Hybrids of Alternately Linked 2,5-Pyrrolylenes and 3,4-Thienylenes"
      K. Kise, F. Chen, K. Kato, T. Tanaka, A. Osuka,
      Chem. Lett. 2017, 46, 1319-1322. (DOI: 10.1246/cl.170511)
    12. "Spontaneous Formation of an Air-Stable Radical upon the Direct Fusion of Diphenylmethane to a Triarylporphyrin"
      K. Kato, W. Cha, J. Oh, K. Furukawa, H. Yorimitsu, D. Kim, A. Osuka,
      Angew. Chem. Int. Ed. 2016, 55, 8711-8714. (DOI: 10.1002/anie.201602683)
    13. "Triphenylsilane-fused Porphyrins"
      K. Kato, J. O. Kim, H. Yorimitsu, D. Kim, A. Osuka,
      Chem. Asian J. 2016, 11, 1738-1746. (DOI: 10.1002/asia.201600424)
    14. "Porphyrin Analogues of a Trityl Cation and Anion"
      K. Kato, W. Kim, D. Kim, H. Yorimitsu, A. Osuka,
      Chem. Eur. J. 2016, 22, 7041-7045. (DOI: 10.1002/chem.201600473, Hot Paper)
    15. "Regioselective phenylene-fusion reactions of Ni(II)-porphyrins controlled by an electron-withdrawing meso-substituent"
      N. Fukui, S.-K. Lee, K. Kato, D. Shimizu, T. Tanaka, S. Lee, H. Yorimitsu, D. Kim, A. Osuka,
      Chem. Sci. 2016, 7, 4059-4066. (DOI: 10.1039/c5sc04748j)
    16. "Peripherally Silylated Porphyrins"
      K. Kato, K. Fujimoto, H. Yorimitsu, A. Osuka,
      Chem. Eur. J. 2015, 21, 13522-13525. (DOI: 10.1002/chem.201502563, Hot Paper)

    総説等 / Reviews & Book chapters

    1. "Porphyrinoid-Based Diradicaloids"
      K. Kato, A. Osuka,
      in Diradicaloids (Ed.: J. Wu), Jenny Stanford Publishing, Singapore, 2022, pp. 453-503 (Chapter 11). (ISBN: 9789814968089)
    2. "Platforms for Stable Carbon-Centered Radicals"
      K. Kato, A. Osuka,
      Angew. Chem. Int. Ed. 2019, 58, 8978-8986. (DOI: 10.1002/anie.201900307)


    他の業績 / Others

    招待講演 / Invited presentations

    1. “π共役骨格の立体配置に基づく新規有機分子の合成と物性評価”
      加藤 研一,
      日本化学会 第104春季年会, 日本大学 理工学部船橋キャンパス, 2024/03/21. (第38回若い世代の特別講演会)
    2. “π共役骨格の配置を指針とした新規有機分子の創出”
      加藤 研一,
      日本化学会中国四国支部 化学講演会, 広島大学 東広島キャンパス, 2023/07/25.
    3. “Chiroptical properties and multifold arylation of pillar[n]arenes”
      Kenichi Kato, Tomoya Kaneda, Yuta Kurakake, Shunsuke Ohtani, Tomoki Ogoshi,
      The Joint Conference on Calixarenes and Cucurbiturils (JCCC 2023), Tel Aviv, Israel, 2023/07/18.
    4. “空気安定な高スピン有機ラジカル、分子の対称性とキラル光学特性”
      加藤 研一,
      高密度共役若手会 オンラインセミナー, オンライン, 2023/07/04.
    5. “Molecular Symmetry and Chiroptical Response in Oligomeric π-Conjugated Systems”
      Kenichi Kato,
      The 9th International Kyoto Symposium on Organic Chemistry (IKSOC), Kyoto, Japan, 2022/11/09.
    6. “Organic Triplet Diradical with Chemical and Magnetic Robustness”
      Kenichi Kato,
      Reaxys PhD Prize Symposium 2020, Online, 2020/10/01.

    すべての講演・発表等のリスト: researchmap

    その他 / Others

    1. 特願2021-059152（出願日：2021/03/31、出願人：豊田合成株式会社、国立大学法人京都大学）、特開2022-155764
      発明の名称：ポリロタキサン及び架橋ポリロタキサン
      発明者：瀬尾 明繁、玉井 秀樹、生越 友樹、加藤 研一、大西 克知、足立 佳祐

    研究費 / Grants

    1. 2023/06 - 2024/05Chiroptical properties and multifold arylation of pillar[n]arenes
      京都大学教育研究振興財団 令和5年度国際研究集会発表助成、350千円
      （The Kyoto University Foundation、財団Website）
    2. 2023/06 - 2024/05立体π共役骨格の高分子化とその吸着性能評価
      徳山科学技術振興財団 スタートアップ助成（2023年度）、1,000千円
      （Tokuyama Science Foundation、財団Website）
    3. 2023/04 - 2025/03ねじれた結合を有する三回対称分子の充填による高密度共役結晶の創出（23H04027）
      日本学術振興会 令和5(2023)年度 学術変革領域研究（A）公募研究、6,000千円
      （学術変革領域研究（A）「高密度共役の科学：電子共役概念の変革と電子物性をつなぐ」）
    4. 2022/04 - 2026/03明確な構造を有する共有結合性一次元ナノチューブの精密設計と機能開拓（22H00334）
      日本学術振興会 令和4(2022)年度 基盤研究(A)、1,250千円（研究分担者）
      5.
    5. 2021/04 - 2022/03剛直な柱状分子がつくる空隙を利用した小分子吸着剤の開発
      増屋記念基礎研究振興財団 2021年度研究助成、500千円
      （Masuyakinen basic research foundation、財団Website）
    6. 2021/04 - 2024/03プロペラ型分子を用いた多環π共役面で囲まれた空間の創出（21K14611）
      日本学術振興会 令和3(2021)年度 若手研究、3,500千円
    7. 2020/10 - 2022/03双極子の環状整列に基づく有機分子性キラル光学特性の制御（20K22528）
      日本学術振興会 令和2(2020)年度 研究活動スタート支援、2,200千円
    8. 2020/10 - 2021/09アレン骨格に基づく磁性有機分子の開拓
      有機合成化学研究所 令和2年度研究助成費、270千円
      （財団Website）
    9. 2020/04 - 2020/09双極子の環状整列に基づく有機分子性キラル光学特性の制御
      京都大学 若手研究者スタートアップ研究費（2020年度 第I期）、500千円
    10. 2017/04 - 2020/03平面芳香族性に限定されない新規縮環ポルフィリンの創出（17J09048）
      日本学術振興会 特別研究員奨励費、2,800千円

    KAKEN (MEXT & JSPS): 10879406

    ＊本ページに記載した金額は、配分総額ではなく直接経費です。